Angelina Jolie is the latest celebrity to appear in Louis Vuitton's Core Values campaign.

The 35-year-old actress follows Bono and his wife Ali Hewson, Sean Connery and Francis Ford Coppola and his daughter Sofia in posing for the luxury brand and Pietro Beccari, Louis Vuitton's executive vice president, is looking forward to showing a different side to the star.

Of the campaign which shows Angelina barefoot, wearing her own clothes and carrying her personal monogrammed Alto bag, he told WWD: "People are not used to seeing Angelina in this situation. I like the fact that it's a real moment. This travel message we give through personal journeys is a fundamental one for the brand.

"This campaign is about a very special person and a very special Journey."

Although the Alto bag featured in the campaign is no longer in production, Pietro explained "we are considering to re-edit it".

The pictures - taken by celebrity photographer Annie Leibovitz in Siem Reap, Cambodia - will be released internationally on Wednesday (15.06.11).

Angelina has donated an undisclosed portion of her fees to a charity.