Angelina Jolie's ex-girlfriend, model Jenny Shimizu, has tied the knot just days after the actress married longtime love Brad Pitt.

The Tomb Raider star and Pitt exchanged vows during a private, intimate ceremony at their estate in Correns, France on 23 August (14), and the following week (ends31Aug14), Shimizu wed socialite Michelle Harper in New York City.

The former Calvin Klein model met brand consultant Harper in 2012, and photos of Harper in a voluminous wedding gown and walking in the streets of the Big Apple were released Wednesday (03Sep14).

Jolie and Shimizu first met on the set of their 1996 film Foxfire, and the actress famously stated in an interview with Girlfriends magazine in 1997 that she "probably have married Jenny Shimizu if I hadn't married my husband" of the time, British actor Jonny Lee Miller.

Jolie added, "I fell in love with her the first second I saw her."

Jolie and Miller wed in 1996, but separated the following year and finalised their divorce in 1999.